Electro-catalytic oxidation of phenol with Ti-base lead dioxide electrode

The Ti-base PbO2 electrode prepared by electrodeposition of PbO2 on the surface of titanium was used for electro-catalytic oxidation of phenol in waste water. The experimental results show that the electrodeposition of PbO2 at a higher current density for a short time, then followed by a lower current density can get a compact and combinative PbO2 layer. The properties of a Ti/PbO2 electrode with an interlayer of oxide are the best. When this kind of electrode is used to treat phenol containing waste water, the phenol-removal rate is higher and the slot voltage is lower. In addition, by using the phenol-removal rate as an index, the influences of electrolysis current density, mass transfer condition and pH were studied and the optimal condition was confirmed.

作 者： 王東田 魏杰 于秀娟 楊紅   作者單位： Dept. of Applied Chemistry, Harbin Institute of Technology, Harbin 150001, China  刊 名： 哈爾濱工業大學學報(英文版)  EI 英文刊名： JOURNAL OF HARBIN INSTITUTE OF TECHNOLOGY(NEW SERIES)  年，卷(期)： 2003 10(1)  分類號： X703  關鍵詞： electro-catalysis   Ti-base oxide electrode   phenol