New Asymmetric Synthesis of Alkannin and Shikonin

A new approach for asymmetric synthesis of alkannin and shikonin is presented. The chiral centers of the targets were introduced via an asymmetric C-arylation of protected chiral glyceraldehyde in high de. The two enantiomers were prepared with the D-isopropylideneglyceraldehyde as the starting material.

作 者： Jian Gang ZHANG Qun LU Wen Hu DUAN Jun Cao CAI   作者單位： Shanghai Institute of Materia Medica, Shanghai Institutes for Biological Sciences, Graduate School of the Chinese Academy of Science Chinese Academy of Sciences,, Shanghai 201203  刊 名： 中國化學快報（英文版）  ISTIC SCI 英文刊名： CHINESE CHEMICAL LETTERS  年，卷(期)： 2005 16(4)  分類號：   關鍵詞： Asymmetric synthesis   alkannin   shikonin   arylglycerols  

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