Study on Synthesis and Intercalation Behavior of Layered Zirconium Proline-N-methylphosphonate-phosphate

Zirconium proline-N-methylphosphonate-phosphate (α-ZPMPP) was prepared in the presence of HF for the first time. The α-ZPMPP sample is highly crystallized with interlayer distance of 1.52 nm. The interlayer distance of complex of α-ZPMPP with n-butylamine (α-ZPMPP-BA) is in 0.45 nm larger than that of α-ZPMPP. The α-ZPMPP possesses different intercalation behavior of host-guest compound from α-ZP.

作 者： Xiao Ping RAO Xiang Kai FU Kai RAO   作者單位： College of Chemistry and Chemical Engineering,South-West China Normal University,Chongqing 400715  刊 名： 中國化學快報(英文版)  ISTIC SCI 英文刊名： CHINESE CHEMICAL LETTERS  年，卷(期)： 2004 15(7)  分類號：   關鍵詞： Zirconium proline-N-methylphosphonate-phosphate   n-butylamine   intercalation complex   interlayer distance   host-guest compound  

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